The pressure is on to make metallic hydrogen
Scientists are closing in on turning hydrogen into a metal in liquid or solid form
UNDER PRESSURE Physicists use powerful electrical pulses in the Z machine at Sandia National Laboratories to create liquid metallic hydrogen for fleeting moments.
RANDY MONTOYA/SANDIA LABS
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In a few highly specialized laboratories, scientists bombard matter with the world’s most powerful electrical pulses or zap it with sophisticated lasers. Other labs squeeze heavy-duty diamonds together hard enough to crack them.
All this is in pursuit of a priceless metal. It’s not gold, silver or platinum. The scientists’ quarry is hydrogen in its most elusive of forms.
Several rival teams are striving to transform hydrogen, ordinarily a gas, into a metal. It’s a high-stakes, high-passion pursuit that sparks dreams of a coveted new material that could unlock enormous technological advances in electronics.
“Everybody knows very well about the rewards you could get by doing this, so jealousy and envy [are] kind of high,” says Eugene Gregoryanz, a physicist at the University of Edinburgh who’s been hunting metallic hydrogen for more than a decade.
Metallic hydrogen in its solid form, scientists propose, could be a superconductor: a material that allows electrons to flow through it effortlessly, with no loss of energy. All known superconductors function only at extremely low temperatures, a major drawback. Theorists suspect that superconducting metallic hydrogen might work at room temperature. A room-temperature superconductor is one of the most eagerly sought goals in physics; it would offer enormous energy savings and vast improvements in the transmission and storage of energy.
Metallic hydrogen’s significance extends beyond earthly pursuits. The material could also help scientists understand our own solar system. At high temperatures, compressed hydrogen becomes a metallic liquid — a form that is thought to lurk beneath the clouds of monstrous gas planets, like Jupiter and Saturn. Sorting out the properties of hydrogen at extreme heat and high pressure could resolve certain persistent puzzles about the gas giants. Researchers have reported brief glimpses of the liquid metal form of hydrogen in the lab — although questions linger about the true nature of the material.
While no lab has yet produced solid metallic hydrogen, the combined efforts of many scientists are rapidly closing in on a more complete understanding of the element itself — as well as better insight into the complex inner workings of solids.
At room temperature and atmospheric pressure, hydrogen is a gas. But like other materials, altered conditions can transform hydrogen into a solid or a liquid. With low enough temperatures or a sufficiently forceful squeeze, hydrogen shape-shifts into a solid. Add heat while squeezing, and it becomes a liquid.
If subjected to still more extreme conditions, hydrogen can — at least theoretically — undergo another transformation, into a metal. All metals have one thing in common: They conduct electricity, due to free-flowing electrons that can go where they please within the material.
Squeeze anything hard enough and it will become a metal. “Pressure does a great job of dislodging the outer electrons,” Ashcroft says. This is what scientists are aiming to do with hydrogen: create a sloshing soup of roving electrons in either a liquid or a solid.
When hydrogen is compressed, many atoms begin to interact with one another, while paired in molecules of two hydrogen atoms each. The underlying physics becomes a thorny jumble. “It is amazing; the stuff takes up incredibly complex arrangements in the solid state,” says Ashcroft, the first scientist to propose, in 1968, that metallic hydrogen could be a high-temperature superconductor.
Hydrogen’s complexity fascinates scientists. “It’s not just the metallization question that’s of interest to me,” says Russell Hemley, a chemist at the Carnegie Institution for Science in Washington, D.C., and Lawrence Livermore National Laboratory in California. Studying the intricacies of hydrogen’s behavior can help scientists refine their understanding of the physics of materials.
In 1935, when physicists Eugene Wigner and Hillard Bell Huntington of Princeton University first predicted that compressed solid hydrogen would be metallic, they thought the transition to a metal might occur at a pressure 250,000 times that of Earth’s atmosphere. That may sound like a lot, but scientists have since squeezed hydrogen to pressures more than 10 times as high — and still no solid metal.
Scientists originally expected that the transition would be a simple flip to metallic behavior. Not so, says theoretical physicist David Ceperley of the University of Illinois at Urbana-Champaign. “Nature has a lot more possibilities.” Solid hydrogen exists in multiple forms, each with a different crystal structure. As the pressure climbs, the wily hydrogen molecules shift into ever-more-complex arrangements, or phases. (For physicists, the “phase” of matter goes deeper than the simple states of solid, liquid or gas.) The number of known solid phases of hydrogen has grown steadily as higher pressures are reached, with four phases now well established. The next phase scientists find could be a metal — they hope.
All this is in pursuit of a priceless metal. It’s not gold, silver or platinum. The scientists’ quarry is hydrogen in its most elusive of forms.
Several rival teams are striving to transform hydrogen, ordinarily a gas, into a metal. It’s a high-stakes, high-passion pursuit that sparks dreams of a coveted new material that could unlock enormous technological advances in electronics.
“Everybody knows very well about the rewards you could get by doing this, so jealousy and envy [are] kind of high,” says Eugene Gregoryanz, a physicist at the University of Edinburgh who’s been hunting metallic hydrogen for more than a decade.
Metallic hydrogen in its solid form, scientists propose, could be a superconductor: a material that allows electrons to flow through it effortlessly, with no loss of energy. All known superconductors function only at extremely low temperatures, a major drawback. Theorists suspect that superconducting metallic hydrogen might work at room temperature. A room-temperature superconductor is one of the most eagerly sought goals in physics; it would offer enormous energy savings and vast improvements in the transmission and storage of energy.
Metallic hydrogen’s significance extends beyond earthly pursuits. The material could also help scientists understand our own solar system. At high temperatures, compressed hydrogen becomes a metallic liquid — a form that is thought to lurk beneath the clouds of monstrous gas planets, like Jupiter and Saturn. Sorting out the properties of hydrogen at extreme heat and high pressure could resolve certain persistent puzzles about the gas giants. Researchers have reported brief glimpses of the liquid metal form of hydrogen in the lab — although questions linger about the true nature of the material.
While no lab has yet produced solid metallic hydrogen, the combined efforts of many scientists are rapidly closing in on a more complete understanding of the element itself — as well as better insight into the complex inner workings of solids.
Not so simple
Hydrogen, the first element in the periodic table and the most common element in the universe, ought to be easy to understand: a single proton paired with a single electron. “What could be more simple than an assembly of electrons and protons?” asks theoretical physicist Neil Ashcroft of Cornell University. But at high pressures, the physics of hydrogen rapidly becomes complex.At room temperature and atmospheric pressure, hydrogen is a gas. But like other materials, altered conditions can transform hydrogen into a solid or a liquid. With low enough temperatures or a sufficiently forceful squeeze, hydrogen shape-shifts into a solid. Add heat while squeezing, and it becomes a liquid.
If subjected to still more extreme conditions, hydrogen can — at least theoretically — undergo another transformation, into a metal. All metals have one thing in common: They conduct electricity, due to free-flowing electrons that can go where they please within the material.
Exotic forms of hydrogen
Under ordinary conditions, in a region too small to be seen on this chart, hydrogen is a gas. At very high temperatures, it becomes liquid. At high pressures, it’s a solid in one of several phases. Scientists expect that it will become a solid metal at pressures not yet reached.
Source: I.F. Silvera/Harvard Univ.
ADAPTED BY E. CONOVER AND J. HIRSHFELD
Source: I.F. Silvera/Harvard Univ.
When hydrogen is compressed, many atoms begin to interact with one another, while paired in molecules of two hydrogen atoms each. The underlying physics becomes a thorny jumble. “It is amazing; the stuff takes up incredibly complex arrangements in the solid state,” says Ashcroft, the first scientist to propose, in 1968, that metallic hydrogen could be a high-temperature superconductor.
Hydrogen’s complexity fascinates scientists. “It’s not just the metallization question that’s of interest to me,” says Russell Hemley, a chemist at the Carnegie Institution for Science in Washington, D.C., and Lawrence Livermore National Laboratory in California. Studying the intricacies of hydrogen’s behavior can help scientists refine their understanding of the physics of materials.
In 1935, when physicists Eugene Wigner and Hillard Bell Huntington of Princeton University first predicted that compressed solid hydrogen would be metallic, they thought the transition to a metal might occur at a pressure 250,000 times that of Earth’s atmosphere. That may sound like a lot, but scientists have since squeezed hydrogen to pressures more than 10 times as high — and still no solid metal.
Scientists originally expected that the transition would be a simple flip to metallic behavior. Not so, says theoretical physicist David Ceperley of the University of Illinois at Urbana-Champaign. “Nature has a lot more possibilities.” Solid hydrogen exists in multiple forms, each with a different crystal structure. As the pressure climbs, the wily hydrogen molecules shift into ever-more-complex arrangements, or phases. (For physicists, the “phase” of matter goes deeper than the simple states of solid, liquid or gas.) The number of known solid phases of hydrogen has grown steadily as higher pressures are reached, with four phases now well established. The next phase scientists find could be a metal — they hope.
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